Total synthesis of (-)-trans-kumausyne

DOI: 10.1016/00404-0399(50)1100V-

Source and publish data:

Tetrahedron Letters p. 5789 - 5792 (1995)

Update date:2022-07-31

Topics:

Authors:

Osumi, Kenji

Sugimura, Hideyuki

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Article abstract of DOI:10.1016/00404-0399(50)1100V-

The total synthesis of (-)-trans-kumausyne has been accomplished in an enantiospecific fashion starting from an L-arabinose derivative. The key step is the stereoselective formation of the substituted tetrahydrofuran via novel cyclization of the β-silyl c

Full text of DOI:10.1016/00404-0399(50)1100V-

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