
Tetrahedron Letters p. 5789 - 5792 (1995)
Update date:2022-07-31
Topics:
Osumi, Kenji
Sugimura, Hideyuki
The total synthesis of (-)-trans-kumausyne has been accomplished in an enantiospecific fashion starting from an L-arabinose derivative. The key step is the stereoselective formation of the substituted tetrahydrofuran via novel cyclization of the β-silyl c
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