Acid-promoted C1-C2 Bond Fission and Subsequent 1,5-Sulfenyl Shift of 1-Acceptor-1-sulfenyl-substituted 2-Vinylcyclopropanes. Formation of 6-Sulfenyl-α,β-γ,δ-unsaturated Carboxylic Esters and Nitriles

DOI: 10.1246/cl.1995.459

Source and publish data:

Chemistry Letters p. 459 - 460 (1995)

Update date:2022-08-03

Topics:

Authors:

Kataoka, Tadashi

Matsumoto, Harutoshi

Iwama, Tetsuo

Shimizu, Hiroshi

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Article abstract of DOI:10.1246/cl.1995.459

1-Acceptor-1-sulfenyl-substituted 2-vinylcyclopropanes were isomerized to 6-sulfenyl-α,β-γ,δ-unsaturated carboxylic esters and nitriles via a C₁-C₂ bond fission and via a 1,5-sulfenyl shift using an acid catalyst.

Full text of DOI:10.1246/cl.1995.459

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