Diastereoselective aldol reactions of chiral aldehydes and chiral methyl ketones: Dependence of stereoselectivity on the metal enolate, the aldehyde 2,3-stereochemistry, and the aldehyde β-alkoxy protecting group

DOI: 10.1016/0040-4039(95)00626-N

Source and publish data:

Tetrahedron Letters p. 3443 - 3446 (1995)

Update date:2022-07-30

Topics:

Authors:

Gustin, Darin J.

VanNieuwenhze, Michael S.

Roush, William R.

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Article abstract of DOI:10.1016/0040-4039(95)00626-N

The stereoselectivity of aldol reactions of chiral aldehydes 5 and 11 with methyl ketone enolates is highly dependent on the aldehyde 2,3-stereochemistry, the aldehyde β-alkoxy protecting group, and the metal enolate. The selectivity trends are rationaliz

Full text of DOI:10.1016/0040-4039(95)00626-N

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