Diastereoselective aldol reactions of chiral aldehydes and chiral methyl ketones: Dependence of stereoselectivity on the metal enolate, the aldehyde 2,3-stereochemistry, and the aldehyde β-alkoxy protecting group

DOI: 10.1016/0040-4039(95)00626-N

Source and publish data:

Tetrahedron Letters p. 3443 - 3446 (1995)

Update date:2022-07-30

Topics:

Authors:

Gustin, Darin J.

VanNieuwenhze, Michael S.

Roush, William R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00626-N

The stereoselectivity of aldol reactions of chiral aldehydes 5 and 11 with methyl ketone enolates is highly dependent on the aldehyde 2,3-stereochemistry, the aldehyde β-alkoxy protecting group, and the metal enolate. The selectivity trends are rationaliz

Full text of DOI:10.1016/0040-4039(95)00626-N

Products guided by the article

Product name:(5S,6S,7R,8S,9S,10R)-3-oxo-7-[(triethylsilyl)oxy]-9-[(tert-butyl-dimethylsilyl)oxy]-11-[(tert-butyl-diphenylsilyl)oxy]-2,6,8,10-tetramethyl-undecan-5-ol

Cas No:169736-72-5

R&D Labs maybe for 169736-72-5

Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China

Relevant to this article

Inhibition of monoamine oxidase by benzoxathiolone analogues

Doi:10.1016/j.bmcl.2016.01.034
(2016)
New [c,d]-fused purinediones: 2-Substituted 9-methyl-4,5-dihydro-6H-8H-pyrimido-[1,2,3-cd]purine-8,10(9H)-diones

Doi:10.1055/s-1995-3996
(1995)
The Reaction of Carbon Disulfide with Diethyl 3-Amino-2-cyano-2-penten-1,5-dicarboxylate: A Convenient Synthesis of Polyfunctionally Substituted Thiophenes andd Their Fused Derivatives

Doi:10.1007/BF00807435
(1995)
An efficient synthesis of optically pure (R)- and (S)-2-(aminomethyl)alanine ((R)- and (S)-Ama) and (R)- and (S)-2-(aminomethyl)leucine ((R)- and (S)-Aml)

Doi:10.1002/hlca.19950780317
(1995)
Enantioselective Diels-Alder cycloadditions with (SS)-2-(p- tolylsulfinyl)-1,4-naphthoquinone: Efficient kinetic resolution of chiral racemic vinylcyclohexenes

Doi:10.1021/jo9811874
(1998)
Doi:10.1021/je00103a028
(1961)

Article Doi