Synthesis of α-Unsubstituted Aldol Adducts Utilizing Enantiomerically Pure β-Keto-δ-Dioxolane Sulfoxides

DOI: 10.1016/0040-4039(95)00853-5

Source and publish data:

Tetrahedron Letters p. 4559 - 4562 (1995)

Update date:2022-08-03

Topics:

Authors:

Blase, Frances Rose

Le, Hung

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00853-5

We report an efficient means to synthesize either enantiomer of α-unsubstituted aldol adduts in high enantiomeric excess through the use of β-keto-δ-dioxolane sulfoxide 4.Through a short sequence of reactions, α-unsubstituted aldol products are obtainable in high yield.

Full text of DOI:10.1016/0040-4039(95)00853-5

Products guided by the article

Product name:1-(2-Methyl-[1,3]dioxolan-2-yl)-3-((R)-toluene-4-sulfinyl)-propan-2-one

Cas No:169888-99-7

R&D Labs maybe for 169888-99-7

NEM CHEMICAL CO.，LTD

website:http://www.NEM.COM.CN

Contact:+86-393-4411771

Address:The west section of shengli Road,Puyang,Henan Province,China
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
wuxi leji biology technology co., LTD

website:http://www.lejibio.com/

Contact:18362718864

Address:The Nanyue Road No. 2, Yixing City, Jiangsu Province
U-Chemo Holding Co.,Limited

website:http://www.u-chemo.com

Contact:+86-21-61558312

Address:Dong Fang Road,
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area

Relevant to this article

Ring opening of epoxides with carboxylates and phenoxides in micellar media catalyzed with Ce(OTf)₄

Doi:10.1081/SCC-120005998
(2002)
Preparation of α- and β-dienyl glycosides used as dienes in aqueous Diels-Alder reactions. Influence of the carbohydrate moiety on the thermodynamics of the reaction

Doi:10.1016/0008-6215(95)00019-P
(1995)
Intramolecular coordination at phosphorus: donor-acceptor interaction in three- and four-coordinated phosphorus compounds

Doi:10.1016/0022-328X(95)00318-K
(1995)
6-Ethylsulfonyl-3-phenylfuro[3,4-d]isoxazole-4(6H)-one: A useful synthon for preparation of heteroanthracyclinone analogues

Doi:10.1016/00404-0399(50)1338-I
(1995)
A Palladium-Mediated Tandem Carbon-Carbon Bond Forming Method Featuring Nucleophilic Substitution of Intermediate ?-Allylpalladium Complexes Produced via the Heck Reaction

Doi:10.1016/0040-4020(95)00518-D
(1995)
Synthesis and Antidiabetic Activity of Thiazolo[2,3-f]Purine Derivatives and Their Analogs

Doi:10.1007/s11094-017-1649-5
(2017)

Article Doi