Total synthesis of (±)-, (-)-, and (+)-oudemansin X

DOI: 10.1248/cpb.43.1111

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1111 - 1118 (1995)

Update date:2022-08-05

Topics:

Authors:

Umezawa Umezawa

Nozawa Nozawa

Nagumo Nagumo

Akita Akita

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Article abstract of DOI:10.1248/cpb.43.1111

Three kinds of oudemansin X, (-)-1, (+)-1 and (±)-1, were totally synthesized. The key point in the present chiral synthesis was the enantioselective acetylation of the racemic alcohols, (±)-5 and (±)-8, using lipase in an organic solvent. The synthetic (-)-1 was found to exhibit strong antifungal activity against several molds and yeasts.

Full text of DOI:10.1248/cpb.43.1111

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