Reaction of methyl 4,5-epoxy-(2E)-pentenoate with arenes. II. Application to the synthesis of(±)-curcudiol, (±)-curcuphenol, (±)-curcuhydroquinone, and(±)-curcuquinone

DOI: 10.1248/cpb.43.553

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 553 - 558 (1995)

Update date:2022-08-04

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Authors:

Ono Ono

Yamamoto

Akita Akita

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Article abstract of DOI:10.1248/cpb.43.553

Four bisabolane sesquiterpenes, (±)-curcudiol (2), (±)-curcuphenol (3), (±)-curcuhydroquinone (5) and (±)-curcuquinone (6), were synthesized based on the reaction of methyl 4,5-epoxy-(2E)-pentenoate (1) with methoxytoluenes in the presence of boron trifluoride etherate.

Full text of DOI:10.1248/cpb.43.553

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