Chemical and Pharmaceutical Bulletin p. 722 - 728 (1995)
Update date:2022-07-30
Topics: Mechanisms Examples
Higashiyama
Fujikura
Takahashi
The reaction of organocerium reagents with chiral aliphatic imines derived from (R)-O-methylphenylglycinol afforded the corresponding amines with high diastereoselectivity. In contrast, the reaction of Grignard reagents with chiral 2-alkyl-1,3-oxazolidines derived from (R)-N-methylphenylglycinol afforded the amines with changeover in diastereoselectivity.
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