Rhodium and rhutenium complex with optically active chelate cyclopentadienyl-phosphine bidentate ligands

DOI: 10.1246/cl.1995.833

Source and publish data:

Chemistry Letters p. 833 - 834 (1995)

Update date:2022-08-03

Topics:

Authors:

Kataoka, Yasutaka

Saito, Yoshinori

Nagata, Koji

Kitamura, Kenichi

Shibahara, Atsushi

Tani, Kazuhide

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Article abstract of DOI:10.1246/cl.1995.833

The first optically active cyclopentadienyl-phosphine bidentate ligands (H ligands) in which a diphenylphosphino group and a cyclopentadienyl or an indenyl group are connected by an L-threitol derivative or an (S,S)-trans-1,2-dimethylcyclopentane group have been prepared.The rodium and rhutenium complexes of their anions have been prepared and characterized.

Full text of DOI:10.1246/cl.1995.833

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