A Rapid and Efficient Synthesis of 1,2-trans-β-Linked Glycosides via Benzyl- or Benzoyl-protected Glycopyranosyl Phosphates

DOI: 10.1039/c39890000685

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 685 - 687 (1989)

Update date:2022-08-03

Topics: Synthesis Efficient Chemical reactions Experimental

Authors:

Hashimoto, Shun-ichi

Honda, Takeshi

Ikegami, Shiro

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Article abstract of DOI:10.1039/c39890000685

A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl t

Full text of DOI:10.1039/c39890000685

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Product name:tetrabenzoylglucopyranosyl diphenyl phosphate

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