Reactions of cis- and cis- with Anhydrous HF and HOTeF5; Compatibility of Phosphine, Alkyl and OTeF5(-) Ligands in Low-valent Transition-metal Complexes

DOI: 10.1039/DT9950002941

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2941 - 2944 (1995)

Update date:2022-08-02

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Authors:

Brewer, Stuart A.

Buggey, Lesley A.

Holloway, John H.

Hope, Eric G.

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Article abstract of DOI:10.1039/DT9950002941

In the reactions of transition metal carbonyl methyls with Hf or HOTeF5 the elimination of methane has been shown to be a strong driving force in the formation of, for example, cis-, cis-, cis- and cis-, which have been characterised by a combination of multinuclear NMR spectroscopic studies.These results also indicate that, with a suitable choice of metals and co-ligands, transition-metal teflate-phosphine and teflate-alkyl complexes can be prepared (teflate = OTeF5(-)).

Full text of DOI:10.1039/DT9950002941

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