Journal of the Chemical Society, Dalton Transactions p. 2941 - 2944 (1995)
Update date:2022-08-02
Topics:
Brewer, Stuart A.
Buggey, Lesley A.
Holloway, John H.
Hope, Eric G.
In the reactions of transition metal carbonyl methyls with Hf or HOTeF5 the elimination of methane has been shown to be a strong driving force in the formation of, for example, cis-a combination of multinuclear NMR spectroscopic studies.These results also indicate that, with a suitable choice of metals and co-ligands, transition-metal teflate-phosphine and teflate-alkyl complexes can be prepared (teflate = OTeF5(-)).
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