Addition of functionalized zinc copper reagents to acetylenic esters: Synthesis of 2-carboalkoxy cyclohexenones

DOI: 10.1016/0040-4039(95)01485-Z

Source and publish data:

Tetrahedron Letters p. 7061 - 7064 (1995)

Update date:2022-08-02

Topics:

Authors:

Crimmins, Michael T.

Huang, Sujuan

Guise, Lisa E.

Borden Lacy

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01485-Z

Conjugate addition of the zinc-copper reagent derived from ethyl 4-iodobutyrate to acetylenic esters in the presence of TMSCl and HMPA results in cyclization and formation of 3-alkyl-2-carboalkoxycyclohexenones in good yields.

Full text of DOI:10.1016/0040-4039(95)01485-Z

Products guided by the article

Product name:2-(1-Methoxymethoxy-hex-5-enyl)-6-oxo-cyclohex-1-enecarboxylic acid ethyl ester

Cas No:172091-70-2

R&D Labs maybe for 172091-70-2

Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA

Relevant to this article

Synthesis of a novel bis-gluco-crown ether derivative

Doi:10.1080/00397919508011451
(1995)
Efficient routes to cyclic 2,3-epoxyalcohols from cycloalkenyl ketones, via cycloalkenyl alcohols

Doi:10.1016/S0040-4020(01)80560-3
(1993)
An improved synthetic preparation of anti conformationally constrained acyclic nucleosides

Doi:10.1081/SCC-100103324
(2001)
HIGHLY DIASTEREOSELECTIVE REDUCTIONS OF N-DIPHENYLPHOSPHINYL IMINES. SYNTHESIS OF AXIAL PRIMARY CYCLIC AMINES.

Doi:10.1016/S0040-4039(00)96795-9
(1987)
Design, synthesis and properties of orthopalladated complexes: Proheterogeneous catalyst

Doi:10.1016/j.poly.2016.02.024
(2016)
Preparation of Cationic (E)-?-Alkenyl Palladium Complexes having a P-O-N or a P-O-P Tridentate Ligand as a Stabilized Intermediate of Palladium-catalysed Stereoselective Addition of Methanol to Acetylenes; Characterisation, X-Ray Analysis and the Reaction Pathway

Doi:10.1039/c39950002099
(1995)

Article Doi