HIGHLY DIASTEREOSELECTIVE REDUCTIONS OF N-DIPHENYLPHOSPHINYL IMINES. SYNTHESIS OF AXIAL PRIMARY CYCLIC AMINES.

DOI: 10.1016/S0040-4039(00)96795-9

Source and publish data:

Tetrahedron Letters p. 5619 - 5622 (1987)

Update date:2022-08-02

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Authors:

Hutchins, Robert O.

Rutledge, Melvin C.

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Article abstract of DOI:10.1016/S0040-4039(00)96795-9

The reduction of N-diphenylphosphinyl imines of substituted cycloalkanones with lithium tri-sec-butylborohydride provides highly diastereoselective conversions to protected axial primary amines which are demasked via cleavage with acid.

Full text of DOI:10.1016/S0040-4039(00)96795-9

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