Metallosilanediols of Molybdenum and Tungsten. Synthesis and Transformation to Functionalized Metallotrisiloxanes. Hydrogen-bonded Structure of

DOI: 10.1039/c39950001917

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1917 - 1920 (1995)

Update date:2022-08-05

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Authors:

Malisisch, Wolfgang

Lankat, Reiner

Fey, Oliver

Reising, Joachim

Schmitzer, Siegfried

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Article abstract of DOI:10.1039/c39950001917

Metallosilanediols <(C5Me5)(OC)2(Me3P)M-SiR(OH)2> (M = Mo, W; R = Me, Ph) react with Me2Si(H)Cl to form metallotrisiloxanes <(C5Me5)(OC)2(Me3P)Mo-Si(R)(OSiMe2H)2> (R = Me, Ph) which are converted to the cyclic bis(metallo)trisiloxanes <(C5Me5)(OC)2(Me3P)M

Full text of DOI:10.1039/c39950001917

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