Chemistry of Molybdenum Complexes with (Triphenylmethyl)allene

DOI: 10.1039/DT9950002351

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2351 - 2358 (1995)

Update date:2022-08-05

Topics:

Authors:

Huang, Bor-Chen

Wu, Iuan-Yuan

Lin, Ying-Chin

Peng, Shie-Ming

Lee, Gene-Hsiang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950002351

The cationic allene complex 5-C5H5)(CO)3(η²-CH2=C=CHCPH3)>BF4 1, was converted into the dihydronaphthyl complex 5-C5H5)(CO)3(C10H7Ph2)> in the presence of KSCN as the major product.When the reaction was carried out at high concentration, the allylic complex 5-C5H5)(CO)2(η³-CH2C(COC10H7Ph2)CHCPh3>> was isolated as a minor product.Reaction of allene with the dihydronaphthyl complex also induced insertion of CO followed by C-C coupling to give the allylic complex 5-C5H5)(CO)2<η³-CH2C(COC10H7Ph2)CH2>>.In CHCl3 migration of the organic moiety on Mo in the dihydronaphthyl to the C5H5 ligand occurred giving 5-C5H4(C10H7Ph2)>(CO)3>.In tetrahydrofuran and MeCN, similar reactions gave 5-C5H4(C10H7Ph2)>(CO)3> and C5H5(C10H7Ph2) respectively.Under thermolytic conditions 5-C5H5)(CO)2(PPh3)> was also converted into 5-C5H4(C10H7Ph2)>(CO)2(PPh3)>.The latter complex and 5-C5H5)(CO)3(C10H7Ph2)> have been characterized by X-ray diffraction analysis.

Full text of DOI:10.1039/DT9950002351

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Mo(η(5)-C5H5)(CO)2(P(OPh)3)(C(O)C10H7Ph2)]

Cas No:172889-61-1

R&D Labs maybe for 172889-61-1

KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China

Relevant to this article

Betulinic acid derivatives: A new class of human immunodeficiency virus type 1 specific inhibitors with a new mode of action

Doi:10.1021/jm950670t
(1996)
First examples of peptidomimetic inhibitors of interleukin-1β converting enzyme

Doi:10.1021/jm9601516
(1996)
Synthesis and nicotinic receptor activity of a hydroxylated tropane

Doi:10.1016/j.bmcl.2003.09.081
(2004)
Acylation-cyclization of allenes

Doi:10.1016/0040-4020(95)00816-Q
(1995)
Pd-Catalyzed ipso, meta-Dimethylation of ortho-Substituted Iodoarenes via a Base-Controlled C-H Activation Cascade with Dimethyl Carbonate as the Methyl Source

Doi:10.1021/jacs.0c13057
(2021)
Doi:10.1007/BF00849327
()

Article Doi