Journal of Organic Chemistry p. 8245 - 8256 (1995)
Update date:2022-09-26
Topics:
Bendiak, Brad
Salayan, Mary E.
Pantoja, Mario
Hydrazine and certain hydrazino derivatives react with sugars having a glycosidic substituent, where the glycosyl moiety is located on a carbon atom adjecent to an aldehyde or keto group of the aglycon, resulting in cleavage of the glycosidic linkage.The reaction proceeds whether the glycon is of the α or β configuration.The released glycosyl moiety, in the presence of excess hydrazino compound, reacts further to give a hydrazone derivative.Removal of the hydrazone group gives the reducing sugar derived from the glycon.
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