The chemistry of platinum hexafluoride. II. Reactions with chlorine trifluoride, bromine pentafluoride, and tetrafluorohydrazine

Article abstract of DOI:10.1021/ic50045a019

Platinum hexafluoride reacts with chlorine trifluoride to give chlorine pentafluoride and the solid ClF₃PtF₅. The infrared spectrum indicates that ClF₃PtF₅ exists in the ionic form ClF₂+PtF₆^-. Platinum hexafluoride reacts with bromine pentafluoride to give fluorine and a black viscous liquid, but no higher bromine fluorides are formed. Tetrafluorohydrazine and platinum hexafluoride react to give nitrogen trifluoride and PtF_4-5.