The chemistry of platinum hexafluoride. II. Reactions with chlorine trifluoride, bromine pentafluoride, and tetrafluorohydrazine

DOI: 10.1021/ic50045a019

Source and publish data:

Inorganic Chemistry p. 1925 - 1927 (1966)

Update date:2022-07-29

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Authors:

Gortsema

Toeniskoetter

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Article abstract of DOI:10.1021/ic50045a019

Platinum hexafluoride reacts with chlorine trifluoride to give chlorine pentafluoride and the solid ClF₃PtF₅. The infrared spectrum indicates that ClF₃PtF₅ exists in the ionic form ClF₂+PtF₆^-. Platinum hexafluoride reacts with bromine pentafluoride to give fluorine and a black viscous liquid, but no higher bromine fluorides are formed. Tetrafluorohydrazine and platinum hexafluoride react to give nitrogen trifluoride and PtF_4-5.

Full text of DOI:10.1021/ic50045a019

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