Journal of the American Chemical Society p. 901 - 905 (1993)
Update date:2022-08-03
Topics:
Hartz, Nikolai
Surya Prakash
Olah, George A.
The reaction mechanism of singlet and triplet methylene with benzene and related aromatic compounds was investigated by kinetic isotope effects (KIEs), solvent effects, and product studies. The results are further rationalized by a series of ab initio calculations at MP2/6-31G*//RHF/6-31G* and UMP2/6-31G*//UHF/6-31G* levels of theory. The proposed 1c intermediate for the triplet reaction was found by means of the calculations, whereas no singlet analog 1 could be found.
View Morewebsite:http://www.shochem.com
Contact:021-50800795
Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Tianjin Boron PharmaTech Co.,Ltd.(expird)
Contact:86-022-59845187
Address:B9-401, Tianda Science Park,No.80,4th Avenue,TEDA,Tianjin, China
Wuhan Silworld Chemical Co.,Ltd
website:http://www.silworldchemical.com
Contact:+86-27-85613400
Address:No.198 jiangjun Road, Wuhan,China 430033
Laohekou Jinghong Chemical Co.,Ltd
Contact:+86-0710-3702747
Address:163.East，Huagong Road，Laohekou
Contact:+86-13914766747
Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Doi:10.1021/jm960249k
(1996)Doi:10.1039/p19960000213
(1996)Doi:10.1021/ja00989a028
(1967)Doi:10.1016/j.jfluchem.2018.06.010
(2018)Doi:10.1039/jr9300001419
(1930)Doi:10.1016/j.tet.2012.06.078
(2012)
