Synthetic study of ciguatoxin. Absolute configuration of the C2 hydroxy group

DOI: 10.1016/S0040-4020(97)00071-9

Source and publish data:

Tetrahedron p. 3057 - 3072 (1997)

Update date:2022-08-03

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Authors:

Oguri, Hiroki

Hishiyama, Shojiro

Sato, Ohki

Oishi, Tohru

Hirama, Masahiro

Murata, Michio

Yasumoto, Takeshi

Harada, Nabuyuki

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Article abstract of DOI:10.1016/S0040-4020(97)00071-9

The absolute stereochemistry of the secondary alcohol of the 1,2-dihydroxybutenyl substituent of ciguatoxin (1) was shown to be S by comparing (he split CD curve of ciguatoxin tetra-p-bromobenzoate (2) with those of di- and tri-p-bromobenzoates of AB ring fragments that were synthesized enaotioselectively.

Full text of DOI:10.1016/S0040-4020(97)00071-9

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