Heterocycles p. 165 - 168 (1996)
Update date:2022-08-03
Topics:
Nemoto, Hideo
Miyata, Junji
Fukumoto, Keiichiro
A novel synthesis of A-ring aromatic trichothecane (2) by the regiocontrolled cyclization of 5-hydroxy-2-(2-methoxymethoxy-4-methylphenyl)-2-methyl-1-methylidenecyclopentane (10), which was prepared via the 2-phenyl-cyclobutanone (6) and cyclobutanols (7 and 8) and the 2-methylidene-3-phenylcyclopentanone (9), was achieved.
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