Tetrahedron Letters p. 2865 - 2868 (1983)
Update date:2022-08-03
Topics:
Hayashi, Tamio
Kabeta, Keiji
Hamachi,Itaru
Kumada, Makoto
(E)-Crotyltrimethylsilane and (E)-cinnamyltrimethylsilane were allowed to react with aldehydes (RCHO: t-Bu, i-Pr, Et, Me) in the presence of titanium chloride to give erythro homoallyl alcohols with over 93percent selectivity.Lower erythroselectivity was observed in the reaction of (Z)-allylsilanes.
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