Novel reduction (Zn-AcOH) of DDHQ esters - A new route to tropone synthesis

DOI: 10.1016/0040-4020(95)01006-8

Source and publish data:

Tetrahedron p. 1707 - 1712 (1996)

Update date:2022-08-02

Topics:

Authors:

Kasturi Kasturi

Palle Palle

Sattigeri

Kumar Kumar

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Article abstract of DOI:10.1016/0040-4020(95)01006-8

Zn/acetic acid reaction of DDHQ esters 1 a-d gave the saturated acids 3 a-d and the hydrocarbons 7 a-d. The intermediacy of the aldehydes 10 and 11 in the formation of the products has been established. Oxidation of hydrocarbons 7a and 7b gave the corresponding tropones (5a and 5b).

Full text of DOI:10.1016/0040-4020(95)01006-8

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