Serendipitous synthesis of a novel cobalt (III) porphyrin phosphoryl complex

DOI: 10.1039/cc9960000173

Source and publish data:

Chemical Communications p. 173 - 174 (1996)

Update date:2022-07-31

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Authors:

Tse, Andy K.-S.

Wang, Ru-Ji

Mak, Thomas C. W.

Chan, Kin Shing

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Article abstract of DOI:10.1039/cc9960000173

A novel complex [bis(dimethylamino)phosphoryl](5,10,15, 20-tetraphenylporphyrinato)cobalt(III) 1 is synthesized serendipitously by the reaction of [Co^III(tpp)Br] with Me₃SiLi (MeLi-Si₂Me₆-HMPA) at -78°C in thf and its structure is characterized by a single-crystal X-ray study.

Full text of DOI:10.1039/cc9960000173

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