Serendipitous synthesis of a novel cobalt (III) porphyrin phosphoryl complex

DOI: 10.1039/cc9960000173

Source and publish data:

Chemical Communications p. 173 - 174 (1996)

Update date:2022-07-31

Topics:

Authors:

Tse, Andy K.-S.

Wang, Ru-Ji

Mak, Thomas C. W.

Chan, Kin Shing

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/cc9960000173

A novel complex [bis(dimethylamino)phosphoryl](5,10,15, 20-tetraphenylporphyrinato)cobalt(III) 1 is synthesized serendipitously by the reaction of [Co^III(tpp)Br] with Me₃SiLi (MeLi-Si₂Me₆-HMPA) at -78°C in thf and its structure is characterized by a single-crystal X-ray study.

Full text of DOI:10.1039/cc9960000173

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis(dimethylamino)phosphoryl(5,10,15,20-tetraphenylporphyrinato)cobalt(III)-dichlormethane (1/1)

Cas No:175551-31-2

R&D Labs maybe for 175551-31-2

SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Shanghai Sharing technologies Co., Ltd.

Contact:86-021-66787223

Address:No11, Lane 225, Jinxiang Road,Pudong district
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China

Relevant to this article

Asymmetric synthesis of chiral spirocyclanes: A new route to the optically active spiro[cyclopentane-1,1′-indan]-2,5-dione system

Doi:10.1016/0040-4039(96)00126-8
(1996)
Facile Synthesis, Triplet-State Properties, and Electrochemistry of Hexaiodo-Subphthalocyanine

Doi:10.1002/chem.201803316
(2018)
15. Total synthesis of (+)-elacomine and (-)-isoelacomine, two hitherto unnamed oxindole alkaloids from Elaeagnus commutata

Doi:10.1002/hlca.19960790116
(1996)
Synthesis, structure, and properties of the stahle and highly acidic dihydrogen complex trans-[Os(η²-H₂)(CH₃CN)(dppe) ₂](BF₄)₂. Perspectives on the influence of the trans ligand on the chemistry of the dihydrogen ligand

Doi:10.1021/om960113k
(1996)
Self-assembled monolayers of compact phosphanes with alkanethiolate pendant groups: Remarkable reusability and substrate selectivity in Rh catalysis

Doi:10.1002/anie.200800884
(2008)
Synthesis, crystal structures, and application of two new pincer type palladium(II)-Schiff base complexes in C-C cross-coupling reactions

Doi:10.1016/j.ica.2017.11.018
(2018)

Article Doi