High yield regioselective ring opening of epoxides using samarium chloride hexahydrate

DOI: 10.1081/SCC-120018790

Source and publish data:

Synthetic Communications p. 1603 - 1610 (2003)

Update date:2022-08-02

Topics:

Authors:

Bhaumik, Kankan

Mali, Umesh W.

Akamanchi

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Article abstract of DOI:10.1081/SCC-120018790

Epoxides were converted to the corresponding β-azidohydrins and β-iodohydrins using SmCl₃·6H₂O/NaN₃ in DMF and SmCl₃·6H₂/NaI in acetonitrile respectively. The reactions were highly regio-selective, ef

Full text of DOI:10.1081/SCC-120018790

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