Iron(III) picolinate-catalyzed oxidative demethylation of N,N- dimethylaniline with hydrogen peroxide in the presence of acetic anhydride

DOI: 10.1248/cpb.45.2089

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2089 - 2092 (1997)

Update date:2022-08-03

Topics:

Authors:

Kotani, Eiichi

Takeya, Tetsuya

Shimizu, Hideaki

Egawa, Hirotaka

Yamamoto, Takeshi

Tobinaga, Seisho

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.45.2089

Oxidation of N,N-dimethylaniline (1) utilizing the Fe(PA)₃/H₂O₂/MeCN system and the Fe(ClO₄)₃-9H₂O/PAH-Py/H₂O₂/MeCN system, simple model systems for mono-oxygenases, in the presence of acetic arthydride (Ac₂O) afforded predominantly the N-acetylative demethylation product, N- methylacetanilide (4), along with a few other compounds.

Full text of DOI:10.1248/cpb.45.2089

NII-Electronic Library Service

Products guided by the article

Product name:acetic acid-(2-dimethylamino-phenyl ester)

Cas No:17579-35-0

R&D Labs maybe for 17579-35-0

henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
Chengdu Green Young Biopharmaceutical INC

Contact:+86-28-85337952

Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000

Relevant to this article

First synthesis of C-phenyl N-tert-butyl [¹⁵N]nitrone (PBN-¹⁵N) for the EPR spin trapping methodology

Doi:10.1515/znb-1996-0125
(1996)
Doi:10.1021/ja01617a052
(1955)
Doi:10.1016/0040-4020(68)88079-2
(1968)
New synthesis of both D- and L-3-O-carbamoyl-2-deoxy-4-thioribosides, substrates for β-selective glycosylations

Doi:10.1016/0040-4039(96)00139-6
(1996)
Synthesis of alkynyl-substituted pyrrolidin-1-yloxyl radicals from 1-pyrroline N-oxide nitrones and alkynylmagnesium bromides

Doi:10.1055/s-1996-4199
(1996)
Alkoxide attack on coordinated olefin can be reversible

Doi:10.1021/om950905z
(1996)

Article Doi