A new synthetic method of some acid hydrazide complexes and their adducts

Article abstract of DOI:10.1080/00945719608005116

The electrochemical oxidation of Co, Cu, Zn and Cd in non-aqueous (acetone) solution of cinnamic (CAH) and/or hippuric (HAH) acid hydrazides gave the corresponding 1:2 complexes in very good yields. The advantage of the method is discussed. When a neutral bidentate donor (1, 10-phenanthroline) is present in solution, adducts with 1:1 ratio are formed. The compounds have been characterized on the basis of elemental analyses, electrical conductivity, magnetic and spectral studies. An octahedral structure is proposed for the Co(II) and Cu(II) complexes. Also, the biological activity of the ligands and their metal complexes has been investigated.

Full text of DOI:10.1080/00945719608005116

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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A New Synthetic Method
of Some Acid Hydrazide
Complexes and Their
Adducts
H. E. Mabrouk a , A. A. El-Asmy b , M. I. Khalifa
b & M. Zedan a
a Faculty of Science , Sanaa University , Sanaa,
Yemen AR
b Chemistry Department, Faculty of Science ,
Mansoura University , Mansoura, Egypt
Published online: 21 Aug 2006.
To cite this article: H. E. Mabrouk , A. A. El-Asmy , M. I. Khalifa & M. Zedan
(1996) A New Synthetic Method of Some Acid Hydrazide Complexes and Their
Adducts, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26:3,
423-437, DOI: 10.1080/00945719608005116
To link to this article: http://dx.doi.org/10.1080/00945719608005116
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