Structure and Reactivity of Peroxyl and Sulphoxyl Radicals from Measurement of Oxygen-17 Hyperfine Couplings: Relationship with Taft Substituent Parameters

DOI: 10.1039/ft9908603279

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 3279 - 3286 (1990)

Update date:2022-08-03

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Authors:

Sevilla, Michael D.

Becker, David

Yan, Mengyao

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Article abstract of DOI:10.1039/ft9908603279

A series of peroxyl radicals (ROO.) with substituent groups of varying electron withdrawing power have been investigated using electron paramagnetic resonance spectroscopy.Sixteen carbon-based radicals have been produced, identified and reacted with 17O-l

Full text of DOI:10.1039/ft9908603279

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