Rearrangement reactions of N-phosphinoyl-O-sulfonylhydroxylamines with amines: Detection of a phosphonamidic-sulfonic mixed anhydride intermediate by nuclear magnetic resonance spectroscopy

DOI: 10.1039/CC9960000867

Source and publish data:

Chemical Communications p. 867 - 868 (1996)

Update date:2022-08-05

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Authors:

Harger, Martin J.P.

Sreedharan-Menon, Ramesh

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Article abstract of DOI:10.1039/CC9960000867

An intermediate can be detected by ³¹P NMR spectroscopy when PhRP(O)NHOSO₂Me (R = PhMeCH) forms the rearrangement product RP(O)(NHBu^t)NHPh with Bu^tNH₂ in dilute solution; the intermediate has been ide

Full text of DOI:10.1039/CC9960000867

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