Tetrahedron p. 5765 - 5772 (1996)
Update date:2022-09-26
Topics:
Tamao, Kohei
Kawachi, Atsushi
Tanaka, Yoko
Ohtani, Hitoshi
Ito, Yoshihiko
An (aminosilyl)lithium and the corresponding copper and magnesium reagents serve as a hydroxy anion equivalent through (1) allylic substitution, (2) addition to vinyloxirane, and (3) addition to acetylene, followed by oxidative cleavage of the silicon-carbon bonds. Highly regio- and stereoselective transformations have been achieved in all cases.
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Doi:10.1021/ja00993a054
(1967)Doi:10.1002/anie.199609931
(1996)Doi:10.1016/0040-4039(96)00471-6
(1996)Doi:10.1039/C6SC01621A
(2016)Doi:10.1139/v96-084
(1996)Doi:10.1016/S0022-1139(00)82667-6
(1981)
