Chemistry Letters p. 1197 - 1200 (1983)
Update date:2022-08-05
Topics:
Sakurai, Hideki
Kobayashi, Yoshiteru
Sato, Ryuji
Nakadaira, Yasuhiro
Thermally generated dimethylsilylene reacts with 1,4-diphenyl-1,3-butadiene to give 1,1-dimethyl-4,5-diphenyl-1-silacyclo-2-pentene.A mechanism involving homolytic C-C bond cleavage of the intermediate vinylsilacyclopropane is suggested.Dimethylsilylene also undergoes a novel silylene-silylene exchange reaction with 1-methyl-1,2,3,4,5-pentaphenylsilole.
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