Transalkynylation and catalytic demercuration of bis(alkynyl)mercurials: Two alternative mechanisms

DOI: 10.1039/cc9960001059

Source and publish data:

Chemical Communications p. 1059 - 1060 (1996)

Update date:2022-08-03

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Authors:

Bedford, Robin B.

Hill, Anthony F.

Thompsett, Andrew R.

White, Andrew J. P.

Williams, David J.

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Article abstract of DOI:10.1039/cc9960001059

The complexes [RhCl(CO)(PPh₃)₂] and [MHCl(CO)(PPh₃)₃] (M = Ru, Os) catalyse the demercuration of [Hg(C≡CR)₂] (R = Ph, C₆H₄Me-4, Buⁿ) to provide buta-1,3-diynes, howeve

Full text of DOI:10.1039/cc9960001059

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