Synthesis p. 652 - 666 (1996)
Update date:2022-09-26
Topics:
Smith, Nicholas D.
Kocienski, Philip J.
Street, Stephen D. A.
Key steps in a stereoselective synthesis of Herboxidiene A, a diastereoisomer of the natural herbicide Herboxidiene, include a Hoppe homoaldol reaction, a copper(I)-mediated 1,2-metallate rearrangement, and a one-pot synthesis of a diene fragment from condensation of a lithiated benzothiazolyl sulfone and an aldehyde.
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(2012)
