Tetrahedron Letters p. 3545 - 3548 (1996)
Update date:2022-07-29
Topics:
Du, Shoucheng
Plat, Dorit
Baasov, Timor
Stereospecific chemical synthesis of the Kdo structure was demonstrated using a mechanism similar to that suggested for the enzyme Kdo8P synthase. The derivative of D-(-)-arabinose (compound 3), in which the enolpyruvate moiety is attached at C-3 hydroxyl, was synthesized in 12 chemical steps and an intramolecular condensation of enolpyruvate and aldehyde functions was examined, under Lewis acid conditions.
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