RSC Advances p. 44274 - 44281 (2015)
Update date:2022-07-29
Topics:
Singh, Hemant Kumar
Singh, Sachin Kumar
Nandi, Rajib
Singh, Madan Kumar
Kumar, Vijay
Singh, Ranjan K.
Rao, D. S. Shankar
Prasad, S. Krishna
Singh, Bachcha
The synthesis and mesomorphic properties of forty substituted aroylhydrazones with peripheral mono-, di- and tri- alkoxy chains derived from a p-amino aroylhydrazone core are described. The compounds with two side chains exhibited a smectic A phase, while the compounds with six soft alkoxy side chains at symmetrical positions formed a rectangular columnar mesophase. The structures of these mesophases were confirmed by differential scanning calorimetry (DSC) analysis, polarized optical microscopy (POM) and powder X-ray diffraction (XRD) studies. Raman studies with the help of density functional theory on some of the mesogenic members have been performed to understand the changes in the intermolecular interactions during phase transitions. A structure-property relationship has been deduced, and mesogenic properties are found to be dependent on the chain length, density and position of the alkoxy chains around the molecular core.
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