Dalton Transactions p. 7320 - 7327 (2016)
Update date:2022-07-29
Topics:
Bilyachenko, Alexey N.
Yalymov, Alexey I.
Korlyukov, Alexander A.
Long, Jér?me
Larionova, Joulia
Guari, Yannick
Vologzhanina, Anna V.
Es'kova, Marina A.
Shubina, Elena S.
Levitsky, Mikhail M.
Fine-tuning of the reaction between alkali metal siloxanolate [PhSi(O)ONa]n and [Ni(NH3)6]Cl2 allowed us to design new hexa- [(PhSiO1,5)12(NiO)6(H2O)(DMSO)9] (1) and pentanuclear [(PhSiO1,5)10(NiO)5(NaOH)(DMF)7] (2) cage-like silsesquioxanes. Their specific structures were studied by single crystal X-ray diffraction and topological analyses. Compound 2 is the first example of a pentanuclear "cylinder"-like metallasilsesquioxane. Magnetic property investigations demonstrate the presence of a slow relaxation of the magnetization, induced by spin glass-like behavior in both cases.
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