Tetrahedron p. 8233 - 8244 (1996)
Update date:2022-08-03
Topics:
Barton, Derek H.R.
Gero, Stephane D.
Holliday, Pascale
Quiclet-Sire, Beatrice
The preparation of cyclohexanoids and cyclopentanoids, potential precursors of biologically interesting molecules is described. The key step of the synthesis is an exo cyclization of 5-hexenyl or 6-heptenyl radicals. The radical, generated by radical exchange from carbohydrate anisyl tellurides (D-galactose or D-arabinose) cyclized into polyhydroxylated cyclohexane or cyclopentane derivatives.
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(2015)
