Synthesis and properties of donor-free bis(difluoromethyl) cadmium, (CF2H)2Cd NMR spectroscopic detection and structure of tetrakis(difluoromethyl) cuprate(III) and related compounds

DOI: 10.1016/S0022-328X(96)06142-6

Source and publish data:

Journal of Organometallic Chemistry p. 7 - 20 (1996)

Update date:2022-08-03

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Authors:

Eujen Eujen

Hoge Hoge

Brauer Brauer

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Article abstract of DOI:10.1016/S0022-328X(96)06142-6

The reaction of CdR₂ (R = Me, Et) with CF₂HI has been investigated. Insertion of difluorocarbene into Cd-C bonds with formation of 1,1-difluoroethyl, 1,1-difluoropropyl and tetrafluoroethyl derivatives is described. Metathesis of CF<

Full text of DOI:10.1016/S0022-328X(96)06142-6

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Product name:N(P(C₆H₅)3)2⁽¹⁺⁾*(CF₃)Cu(CF₂H)3^(1-)=[N(P(C₆H₅)3)2][(CF₃)Cu(CF₂H)3]

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