Journal of Organic Chemistry p. 844 - 849 (1987)
Update date:2022-08-04
Topics:
Katritzky, Alan R.
Kuzmierkiewicz, Wojciech
Aurrecoechea, Jose M.
Readily available (benzothiazol-2-ylthio)(trimethylsilyl)methane (2a) provides a convenient synthon for HSCH2- and enables the general conversions RR'CO -> RR'C(OH)CH(SH)R'' and RBr -> RCH(SH)SiMe3.The lithium derivative of 2a reacts with aldehydes and ketones to give Peterson olefination products which are protected vinyl mercaptans converted into vinyl mercaptans by reaction with methyllithium.This overall conversion is RR'CO -> RR'C:CHSH.
View MoreChengdu Boon Stream Chemical Industry Co.,Ltd.
Contact:+86-28-83156758
Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Jiangsu Feymer Technology Co., Ltd.
Contact:+86-512-58110132
Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Jinan Decheng Hemu Medical Technology Co.，Ltd.
Contact:+86-531-68650525
Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Doi:10.1016/S0960-894X(03)00389-5
(2003)Doi:10.1039/CT9181300020
(1918)Doi:10.1002/hlca.19470300661
(1947)Doi:10.1016/j.catcom.2014.12.006
(2015)Doi:10.3390/molecules190915324
(2014)Doi:10.1021/ja00777a601
(1972)
