Generation of γ-functionalized alkynyl ligands by migratory insertion of an allenylidene unit into a M-OR bond

DOI: 10.1039/CC9960001413

Source and publish data:

Chemical Communications p. 1413 - 1414 (1996)

Update date:2022-07-30

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Authors:

Werner, Helmut

Wiedemann, Ralf

Laubender, Matthias

Wolf, Justin

Windmueller, Bettina

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Article abstract of DOI:10.1039/CC9960001413

The hydroxyrhodium(I) complexes 2a,b, which are prepared from the corresponding chloro derivatives 1a,b and KOBu^t, react with acetic acid and phenol at room temperature to give the new acetato and phenolato metal compounds 3a,b and 4a,b almost

Full text of DOI:10.1039/CC9960001413

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