Total synthesis of phaseolinic acid by enyne cyclization

DOI: 10.1016/0957-4166(96)00231-5

Source and publish data:

Tetrahedron Asymmetry p. 1923 - 1928 (1996)

Update date:2022-09-26

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Authors:

Zhang, Zhaoguo

Lu, Xiyan

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Article abstract of DOI:10.1016/0957-4166(96)00231-5

Enantiopure phaseolinic acid was synthesized from (R)-4'-chloro-1'-n-pentyl-2'-butenyl 3-trimethylsilyl-2-propynoate by palladium (II) catalyzed cyclization reaction as the key step.

Full text of DOI:10.1016/0957-4166(96)00231-5

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Product name:(3R,4R,5R)-5-Pentyl-3-phenylsulfanylmethyl-4-vinyl-dihydro-furan-2-one

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