Cleavage of titanium dimethylamides with methyl iodide

DOI: 10.1021/om00019a057

Source and publish data:

Organometallics p. 2907 - 2909 (1994)

Update date:2022-08-03

Topics:

Authors:

Johnson, Adam R.

Wanandi, Paulus W.

Cummins, Christopher C.

Davis, William M.

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Article abstract of DOI:10.1021/om00019a057

A procedure for converting metal dimethyl-amido complexes into the corresponding metal iodide complexes is described. Treatment of (Me₂N)₂Ti(NRAr)₂ (R = C(CD₃)₂CH₃, Ar = 3,5-C₆H₃Me₂) with excess methyl iodide gave I₂Ti(NRAr)₂ in 60% isolated yield.

Full text of DOI:10.1021/om00019a057

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