The reaction of electrophilic terminal phosphinidene complexes with enolizable ketones : C-H vs O-H vs C-C insertion of phosphorus

DOI: 10.1039/CC9960001903

Source and publish data:

Chemical Communications p. 1903 - 1904 (1996)

Update date:2022-08-03

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Authors:

Inubushi, Yoichi

Huy, Ngoc Hoa Tran

Mathey, Francois

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Article abstract of DOI:10.1039/CC9960001903

Transient [PhP→W(CO)5], as generated from the appropriate 7-phosphanorbornadiene precursor, reacts at 120°C with various enolizable ketones or β-diketones to give the products resulting from the insertion of phosphorus into either the α-CH, the enol OH, o

Full text of DOI:10.1039/CC9960001903

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