First total synthesis and structural elucidation of (-)-goniofupyrone

DOI: 10.1016/0040-4039(96)01085-4

Source and publish data:

Tetrahedron Letters p. 5389 - 5392 (1996)

Update date:2022-08-03

Topics:

Authors:

Mukai, Chisato

Hirai, Syuichi

Kim, In Jong

Hanaoka, Miyoji

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Article abstract of DOI:10.1016/0040-4039(96)01085-4

The first total synthesis of (-)-goniofupyrone, isolated from Goniothalamus giganteus, was accomplished in a stereoselective manner from (+)-tricarbonyl(η⁶-2-trimethylsilylbenzaldehyde)chromium(0) complex. This synthesis unambiguously established the relative and absolute stereochemistry of (-)-goniofupyrone.

Full text of DOI:10.1016/0040-4039(96)01085-4

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