Journal of the Chinese Chemical Society p. 361 - 372 (1997)
Update date:2022-08-02
Topics:
Chou, Shang-Shing P.
Hsu, Chien-Hung
Hydride abstraction of tricarbonyl[η4-1-(phenylsultonyl)-1,3-cyclohexadiene]iron(0) complex 2 with Ph3C+PF6-, regiospecifically provided the title compound 3 in excellent yield. Cationic complex 3 could react with a variety of nucleophiles in good yields. Soft nucleophiles prefer to attack at the C-5 position, whereas hard nucleophiles such as methyllithium and the enolate of ethyl acetate gave the C-5 as well as the C-2 addition products. Some synthetic applications of the addition products were also studied.
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