Journal of the Chemical Society, Dalton Transactions p. 3603 - 3608 (1996)
Update date:2022-08-03
Topics:
Fernandez, Eduardo J.
Gimeno, M. Concepcion
Jones, Peter G.
Laguna, Antonio
Laguna, Mariano
Olmos, Elena
Treatment of [M(CO)4{(Ph2PCH2)2CMe(CH 2PPh2)}] (M = Mo or W) with neutral or cationic gold-(I) or -(III) derivatives afforded bi- or tri-nuclear complexes containing the triphosphine (Ph2PCH2)3CMe (tdppme) acting as a μ-P,P′,P″ ligand, a co-ordination mode poorly represented thus far. The binuclear derivative [(OC)4Mo(tdppme)AuCl] further reacts with 1 equivalent of Tl(acac) (acac = acetylacetonate) to afford [(OC)4Mo(tdppme)Au(acac)]. This complex acts as a deprotonating agent in reactions with various starting materials containing phosphines such as (Ph2P)2CH2 or (Ph2P)3CH, leading to the formation of trinuclear methanide complexes. The crystal structure of [(OC)4Mo(tdppme)AuCl] has been established by X-ray crystallography.
View MoreHangzhou Deli Chemical Co.,Ltd.
website:http://www.dlchemical.com
Contact:86 571 28006267
Address:Tangxi Industrial Area, Yuhang District, Hangzhou
Nanjing Norris Pharm Technology Co., Ltd.
Contact:+86-13901585132
Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Hangzhou Maytime Bio-Tech Co.,Ltd.
website:http://www.maytime.com.cn
Contact:+86-571-88925295 88920965
Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
Ningbo Distant Chemicals Co.,Ltd
Contact:86-574-27862490,27862438
Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)
Contact:+86 021 50106671
Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Doi:10.1016/0040-4039(96)01758-3
(1996)Doi:10.1039/c39800000980
(1980)Doi:10.1063/1.1671734
(1969)Doi:10.1002/ejoc.202000837
(2020)Doi:10.1016/j.tetlet.2011.11.051
(2012)Doi:10.1002/1521-3773(20011203)40:23<4441::AID-ANIE4441>3.0.CO;2-I
(2001)
