Silyl alkylidene complexes free of anionic π ligands (Me3ECH2)2Ta(=CHEMe3)(SiPh 2But) (E = C, Si): PMe3-promoted conversions to bis(alkylidene) complexes through preferential sil

DOI: 10.1039/CC9960002383

Source and publish data:

Chemical Communications p. 2383 - 2384 (1996)

Update date:2022-08-02

Topics:

Authors:

Diminnie, Jonathan B.

Hall, Heather D.

Xue, Ziling

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Silyl alkylidene complexes (Me₃ECH₂)₂Ta(=CHEMe₃)-(SiPh ₂Bu^t) (E = C 1, Si 2) react with PMe₃ to form bis(alkylidene) complexes (Me₃ECH₂)Ta(PMe₃)<

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