Enantioselective total synthesis and absolute configuration of the natural norsesquiterpene 7-demethyl-2-methoxycalamenene by a silane-terminated intramolecular heck reaction

DOI: 10.1002/jlac.199619961207

Source and publish data:

Liebigs Annalen p. 1981 - 1987 (1996)

Update date:2022-08-04

Topics:

Authors:

Tietze, Lutz F.

Raschke, Thomas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/jlac.199619961207

The total synthesis of the norsesquiterpene 7-demethyl-2-methoxycalamenene (1) by a newly developed enantioselective silane-terminated Heck reaction is described. The Pd⁰-catalyzed transformation of the allylsilane 7, obtained from 3-(3-methoxy

Full text of DOI:10.1002/jlac.199619961207

Products guided by the article

Product name:Toluene-4-sulfonic acid 1-((S)-6-methoxy-7-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-ethyl ester

Cas No:185320-27-8

R&D Labs maybe for 185320-27-8

Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road

Relevant to this article

Unconventional acceptor and donor functional groups linked by a captodative spacer

Doi:10.1016/S0040-4020(96)00968-4
(1996)
The synthesis and hybridization properties of an oligonucleotide containing hexafluoroacetone ketal internucleotide linkages

Doi:10.1016/S0040-4039(96)02005-9
(1996)
A facile, safe and inexpensive preparation of S -methyl arylcarbamothioates by methylthiocarbonylation of primary arylamines with O, S -dimethyl carbonodithioate

Doi:10.1055/s-0029-1219226
(2010)
Biaryl formation using the Suzuki protocol: Considerations of base, halide, and protecting group

Doi:10.1016/S0040-4039(96)02065-5
(1996)
Doi:10.1021/jo01256a019
(1969)
Research on antifungal and antimycobacterial agents. Synthesis and activity of 4-alkylthiopyridine-2-carbothioamides

Doi:10.1002/ardp.19963291003
(1996)

Article Doi