Enantioselective total synthesis and absolute configuration of the natural norsesquiterpene 7-demethyl-2-methoxycalamenene by a silane-terminated intramolecular heck reaction

DOI: 10.1002/jlac.199619961207

Source and publish data:

Liebigs Annalen p. 1981 - 1987 (1996)

Update date:2022-08-04

Topics:

Authors:

Tietze, Lutz F.

Raschke, Thomas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/jlac.199619961207

The total synthesis of the norsesquiterpene 7-demethyl-2-methoxycalamenene (1) by a newly developed enantioselective silane-terminated Heck reaction is described. The Pd⁰-catalyzed transformation of the allylsilane 7, obtained from 3-(3-methoxy

Full text of DOI:10.1002/jlac.199619961207

Products guided by the article

Product name:Toluene-4-sulfonic acid 1-((S)-6-methoxy-7-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-ethyl ester

Cas No:185320-27-8

R&D Labs maybe for 185320-27-8

Wuhan Biet Co., Ltd

website:http://www.biet.com.cn/

Contact:+86-27-8369 8488

Address:No. 6, Building 21, China Merchants Fanwang, Sixin North Road, Hanyang District, Wuhan City, Hubei Province
Mascot I.E. Co., Ltd.

website:http://www.mascot-ie.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Jinan Finer Chemical Co., Ltd

website:http://www.finerchem.com

Contact:+86-531-88989536

Address:New Material Industry Park, Jinan Ciyt, China

Relevant to this article

Unconventional acceptor and donor functional groups linked by a captodative spacer

Doi:10.1016/S0040-4020(96)00968-4
(1996)
The synthesis and hybridization properties of an oligonucleotide containing hexafluoroacetone ketal internucleotide linkages

Doi:10.1016/S0040-4039(96)02005-9
(1996)
A facile, safe and inexpensive preparation of S -methyl arylcarbamothioates by methylthiocarbonylation of primary arylamines with O, S -dimethyl carbonodithioate

Doi:10.1055/s-0029-1219226
(2010)
Biaryl formation using the Suzuki protocol: Considerations of base, halide, and protecting group

Doi:10.1016/S0040-4039(96)02065-5
(1996)
Doi:10.1021/jo01256a019
(1969)
Research on antifungal and antimycobacterial agents. Synthesis and activity of 4-alkylthiopyridine-2-carbothioamides

Doi:10.1002/ardp.19963291003
(1996)

Article Doi