Enantioselective total synthesis and absolute configuration of the natural norsesquiterpene 7-demethyl-2-methoxycalamenene by a silane-terminated intramolecular heck reaction

DOI: 10.1002/jlac.199619961207

Source and publish data:

Liebigs Annalen p. 1981 - 1987 (1996)

Update date:2022-08-04

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Authors:

Tietze, Lutz F.

Raschke, Thomas

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Article abstract of DOI:10.1002/jlac.199619961207

The total synthesis of the norsesquiterpene 7-demethyl-2-methoxycalamenene (1) by a newly developed enantioselective silane-terminated Heck reaction is described. The Pd⁰-catalyzed transformation of the allylsilane 7, obtained from 3-(3-methoxy

Full text of DOI:10.1002/jlac.199619961207

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