Transition metal complexes derived from N-anthranilamido-N′-benzoylthiocarbamide (H2ABTC)

Article abstract of DOI:10.1080/00945719608004402

Complexes of N-anthranilamido-N′-benzoylthiocarbamide (H₂ABTC) with Cr(III), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and UO₂(VI) have been synthesized and characterized on the basis of elemental analyses, molar conductivities, spectral (IR and visible) and magnetic studies. IR spectral data show that the ligand behaves in a neutral bidentate, mononegative bidentate or tridentate and binegative tridentate or tetradentate manner. All the complexes are non-electrolytes. Different stereochemistries are proposed for the Cr(III), Mn(II), Co(II), Ni(II) and Cu(II) complexes according to the data of magnetic and electronic spectral measurements. IR data indicate that the carbonyl oxygen of the benzoyl rnoiety is the backbone of the chelating agent in all the complexes.

Full text of DOI:10.1080/00945719608004402

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Transition Metal Complexes
from N-Anthranilamido-
N′-benzoylthiocarbamide
(H2ABTC)
T. H. Rakha a , N. Nawar a & G. M. Abu El-Reash a
a Department of Chemistry, Faculty of Science ,
Mansoura University , Mansoura, 35516, Egypt
Published online: 23 Aug 2006.
To cite this article: T. H. Rakha , N. Nawar & G. M. Abu El-Reash (1996) Transition
Metal Complexes from N-Anthranilamido-N′-benzoylthiocarbamide (H2ABTC),
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26:10,
1705-1718, DOI: 10.1080/00945719608004402
To link to this article: http://dx.doi.org/10.1080/00945719608004402
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