Total synthesis of optically active costaclavine (synthetic studies of indoles and related compounds part 48.)

DOI: 10.1248/cpb.47.1587

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1587 - 1590 (1999)

Update date:2022-09-26

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Authors:

Osanai, Kumi

Yokoyama, Yuusaku

Kondo, Kazuhiro

Murakami, Yasuoki

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Article abstract of DOI:10.1248/cpb.47.1587

The first total synthesis of optically active costaclavine (18), an ergot alkaloid, was accomplished starting from methyl [4R-(Z)]-[4-[[(1,1- dimethylethoxy)carbonyl]methylamino]-3,4-dihydro-1-[(4- methylphenyl)sulfonyl]benz[cd]indol-5(1H)-ylidene]acetate

Full text of DOI:10.1248/cpb.47.1587

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Product name:methyl (4R,5S)-4-[[(1,1-dimethylethoxy)carbonyl]methylamino]-1,3,4,5-tetrahydro-1-[(4-methylphenyl)sulfonyl]benz[cd]indol-5-acetate

Cas No:186084-75-3

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