Stereocontrolled synthesis of 2-amino-2-deoxy-α-D-C-glycopyranosides by radical cyclization reactions

DOI: 10.1016/S0040-4039(96)02153-3

Source and publish data:

Tetrahedron Letters p. 9193 - 9194 (1996)

Update date:2022-07-30

Topics:

Authors:

Czernecki, Stanislas

Ayadi, Ebtissam

Xie, Juan

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Article abstract of DOI:10.1016/S0040-4039(96)02153-3

Radical cyclization of phenyl 2-N-allylamino-3,4,6-tri-O-benzyl-2-deoxy-α-D-1-seleno galacto and gluco pyranosides afforded α-D-C-glycopyranosides with high stereoselectivity involving a 5-exo-trig mechanism.

Full text of DOI:10.1016/S0040-4039(96)02153-3

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