Side-Chain Liquid-Crystalline Polyoxetanes with a Spacer-Separated Azobenzene Moiety. II. Preparation and Characterization of Polyoxetanes Derived from 4-(4-Alkoxyphenylazo)phenyl 4-[7-(3-Methyl-3-oxetanyl)-1,6-dioxaheptyl]-benzoates

Article abstract of DOI:10.1246/bcsj.70.175

A series of polyoxetanes were prepared by the cationic ring-opening polymerization of 4-(4-alkoxyphenylazo)phenyl 4-[7-(3-methyl-3-oxetanyl)-1,6-dioxaheptyl]benzoates using 0.08 molar amount of THF·BF₃ in dichloromethane at 20 to 30° C. Although the product polymers indicated GPC-average molecular weights of around 9000 to 23000, in most cases, they did not have an unimodal molecular weight dispersity. The liquid-crystalline mesophases of the polymers were examined by differential scanning calorimetry and polarized optical microscopy; these textures were observed due to nematic and/or smectic mesophases over a wide temperature range from about 250° C to room temperature. The benzoate moiety, the longer p-substituted alkoxy tails, and the oxetane main chain play important roles in maintaining highly ordered, stable mesophases.